Noncovalent Engineering of Carbon Nanotube Surfaces by Rigid, Functional Conjugated Polymers
Journal of the American Chemical Society2002Vol. 124(31), pp. 9034–9035
Citations Over TimeTop 1% of 2002 papers
Abstract
We report a new nonwrapping approach to noncovalent engineering of carbon nanotube surfaces by short, rigid functional conjugated polymers, poly(aryleneethynylene)s. Our technique not only enables the dissolution of various types of carbon nanotubes in organic solvents, which represents the first example of solubilization of carbon nanotubes via pi-stacking without polymer wrapping, but could also introduce numerous neutral and ionic functional groups onto the carbon nanotube surfaces.
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