The Copper-Catalyzed N-Arylation of Indoles
Journal of the American Chemical Society2002Vol. 124(39), pp. 11684–11688
Citations Over TimeTop 1% of 2002 papers
Abstract
A general method for the N-arylation of indoles using catalysts derived from CuI and trans-1,2-cyclohexanediamine (1a), trans-N,N'-dimethyl-1,2-cyclohexanediamine (2a), or N,N'-dimethyl-ethylenediamine (3) is reported. N-Arylindoles can be produced in high yield from the coupling of an aryl iodide or aryl bromide with a variety of indoles.
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