{Tl[Au(C6Cl5)2]}n: A Vapochromic Complex
Citations Over TimeTop 1% of 2003 papers
Abstract
The X-ray structure of (Tl[Au(C(6)Cl(5))(2)])(n), 1, consists of 1-D linear polymer chains parallel to the crystallographic z axis. The crystal structure of 1 has channels that run parallel to these chains with interatom distances in the range 3.231-4.076 A. There are holes in these channels with diameters as large as 10.471 A, which can accommodate a variety of solvents. Complex 1 displays reversible vapochromic emission and absorption spectral behavior when the solid is exposed to a variety of organic vapors such as acetone, acetonitrile, triethylamine, acetylacetone, tetrahydrothiophene, 2-fluoropyridine, tetrahydrofuran, and pyridine. Complex 1 is luminescent at room temperature and at 77 K in the solid state. UV excitation at 495 nm leads to an emission at 531 nm.
Related Papers
- → Aggregation induced phosphorescence of metal complexes: From principles to applications(2017)208 cited
- → Achieving Colorful Ultralong Organic Room-Temperature Phosphorescence by Precise Modification of Nitrogen Atoms on Phosphorescence Units(2023)34 cited
- → On the nature of tyrosine phosphorescence from proteins(1966)19 cited
- → [11] Application of phosphorescence to the study of proteins(1978)7 cited
- Calculation of Gibbs free energy of iron acetylacetone hydrogenating reaction by density functional theory(2009)