Charge Ordering in Lithium Vanadium Phosphates: Electrode Materials for Lithium-Ion Batteries
Journal of the American Chemical Society2002Vol. 125(2), pp. 326–327
Citations Over TimeTop 10% of 2002 papers
Abstract
The delithiation process in monoclinic Li3V2(PO4)3 has been determined by powder neutron diffraction coupled with 7Li solid-state NMR techniques. Charge ordering of vanadium (V3+/V4+) was observed in Li2V2(PO4)3 as shown by the gray and blue V-O octahedra, respectively, indicating that the electrons are pinned in this phase and hence transport is limited.
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