Highly Regioselective Functionalization of Aliphatic Carbon−Hydrogen Bonds with a Perbromohomoscorpionate Copper(I) Catalyst
Journal of the American Chemical Society2003Vol. 125(6), pp. 1446–1447
Citations Over TimeTop 10% of 2003 papers
Ana Caballero, M. Mar Díaz‐Requejo, Tomás R. Belderraín, M. Carmen Nicasio, Swiatoslaw Trofimenko, Pedro J. Pérez
Abstract
The complex Tp(Br3)Cu(NCMe) (1) is an excellent catalyst for the regioselective carbene transfer reaction to tertiary C-H bonds of hydrocarbons, at room temperature, using the readily available ethyl diazoacetate (EDA) as the carbene source.
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