Formation of the Intermediate-Spin Iron(III) Porphyrin Complexes with (dxz, dyz)3(dxy)(dz2)1 Electron Configuration
Journal of the American Chemical Society2003Vol. 125(43), pp. 13028–13029
Citations Over TimeTop 10% of 2003 papers
Abstract
On the basis of the difference in meso-13C chemical shifts, we have concluded that the intermediate-spin iron(III) complexes with highly ruffled and highly saddled porphyrins have different electron configurations. While the latter has a conventional (dxy)2(dxz, dyz)2(dz2)1, the former adopts a novel (dxz, dyz)3(dxy)1(dz2)1.
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