C−C Bond Cleavage of Acetonitrile by a Dinuclear Copper(II) Cryptate
Journal of the American Chemical Society2004Vol. 126(15), pp. 4760–4761
Citations Over TimeTop 10% of 2004 papers
Abstract
The dinuclear copper(II) cryptate [Cu2L](ClO4)4 (1) cleaves the C-C bond of acetonitrile at room temperature to produce a cyanide bridged complex of [Cu2L(CN)](ClO4)3.2CH3CN.4H2O (2). The cleavage mechanism is presented on the basis of the results of the crystal structure of 2, electronic absorption spectra, ESI-MS spectroscopy, and GC spectra of 1, respectively.
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