Functionalization on Silica Gel with Allylsilanes. A New Method of Covalent Attachment of Organic Functional Groups on Silica Gel
Journal of the American Chemical Society2003Vol. 125(16), pp. 4688–4689
Citations Over TimeTop 10% of 2003 papers
Toyoshi Shimada, Kazuko Aoki, Yo Shinoda, Tomoaki Nakamura, Norihito Tokunaga, Shinji Inagaki, Tamio Hayashi
Abstract
Treatment of an (allyl)organosilane with silica gel in refluxing toluene brought about deallylation forming an Si-O-Si bond with the silicon on the silica gel. This Si-O-Si bond formation provides us with a new reliable method for the functionalization of a silica gel surface.
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