From Azides to Nitro Compounds in a Few Seconds Using HOF·CH3CN
Journal of the American Chemical Society2003Vol. 125(27), pp. 8118–8119
Citations Over TimeTop 10% of 2003 papers
Abstract
HOF.CH3CN, a very efficient oxygen-transfer agent, was reacted with various azides to form the corresponding nitro compounds in excellent yields and in very short reaction times. The respective nitroso derivatives were found to be intermediates in this reaction. When the azides were reacted with MCPBA or DMDO, no reaction took place, and the starting materials were fully recovered.
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