Triquinanes from Linear Alkylidene Carbenes via Trimethylenemethane Diyls
Journal of the American Chemical Society2003Vol. 125(34), pp. 10156–10157
Citations Over TimeTop 21% of 2003 papers
Abstract
The intramolecular [2+3] cycloaddition reaction of the trimethylenemethane diyl generated from the intramolecular cyclopropanation reaction of alkylidene carbene produced linearly fused triquinanes regio- and stereoselectively. The current tandem cycloaddition reaction was applied to a 14-step total synthesis of hirsutene from methallyl alcohol.
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