The Modulating Possibilities of Dicarbollide Clusters: Optimizing the Kharasch Catalysts
Journal of the American Chemical Society2003Vol. 125(39), pp. 11830–11831
Citations Over TimeTop 10% of 2003 papers
Oscar Tutusaus, Clara Viñas, Rosario Núñez, Francesç Teixidor, Albert Demonceau, Sébastien Delfosse, Alfred F. Noels, I. Mata, Elı́es Molins
Abstract
exo-Cluster dicarbollides substitution has allowed tuning of the E degrees (Ru(II)/Ru(III)) potential to obtain the best-performing Kharasch catalyst. We postulate that this is possible through the to-and-fro electron movement between the boron cluster and the sulfonium moieties.
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