Bright Phosphorescence of a Trinuclear Copper(I) Complex: Luminescence Thermochromism, Solvatochromism, and “Concentration Luminochromism”
Journal of the American Chemical Society2003Vol. 125(40), pp. 12072–12073
Citations Over TimeTop 10% of 2003 papers
H. V. Rasika Dias, H.V.K. Diyabalanage, Manal A. Rawashdeh‐Omary, Matthew A. Franzman, Mohammad A. Omary
Abstract
A photophysical study is reported for the trinuclear copper(I) complex {[3,5-(CF3)2Pz]Cu}3. The neutral compound exhibits multicolor bright phosphorescent emissions both in the solid state and in solution. The emission can be tuned to multiple visible colors by controlling the temperature, solvent, and {[3,5-(CF3)2Pz]Cu}3 concentration, giving rise to luminescence thermochromism, luminescence solvatochromism, and a new optical phenomenon called "concentration luminochromism", respectively.
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