Cyclohexane and Benzene Amination by Catalytic Nitrene Insertion into C−H Bonds with the Copper-Homoscorpionate Catalyst TpBr3Cu(NCMe)

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Abstract

The complex TpBr3Cu(NCMe) catalyzes, at room temperature, the insertion of a nitrene group from PhINTs into the carbon-hydrogen bond of cyclohexane and benzene, as well as into the primary C-H bonds of the methyl groups of toluene and mesitylene, in moderate to high yield.

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