A Triplet Carbene Surviving a Week in Solution at Room Temperature
Journal of the American Chemical Society2003Vol. 125(48), pp. 14664–14665
Citations Over TimeTop 10% of 2003 papers
Abstract
A stable triplet carbene, having a lifetime at 25 degrees C of 14.5 days in a dilute benzene solution, was realized by simply changing the substituent at the 10 position of the previously most persistent carbene, di[9-(10-phenyl)anthryl]carbene, from a phenyl to a 2,6-dimethyl-4-tert-butylphenyl group.
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