Convergent Synthesis and Photophysics of [60]Fullerene/Porphyrin-Based Rotaxanes
Journal of the American Chemical Society2004Vol. 126(11), pp. 3388–3389
Citations Over TimeTop 1% of 2004 papers
Abstract
A series of Sauvage-type rotaxanes containing [60]fullerene and tetraarylporphyrin moieties has been synthesized by a convergent route. Photoinduced energy-transfer and electron-transfer reactions in these rotaxanes yield long-lived change-separated states, in agreement with the large distance between the fullerene and porphyrin chromophores.
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