Imidazo[1,5-a]pyridine: A Versatile Architecture for Stable N-Heterocyclic Carbenes
Journal of the American Chemical Society2005Vol. 127(10), pp. 3290–3291
Citations Over TimeTop 1% of 2005 papers
Manuel Alcarazo, Stephen J. Roseblade, A.R. Cowley, Rosario Fernández, John M. Brown, José M. Lassaletta
Abstract
The imidazo[1,5-a]pyridine skeleton provides a versatile platform for the generation of new types of stable N-heterocyclic carbenes. Rh(I) mono- (6) and biscarbenes (7) from imidazo[1,5-a]pyridin-3-ylidenes (ImPy) and derivatives such as 13 from a mesoionic carbene were synthesized and characterized.
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