Highly Efficient Ru−Pseudohalide Catalysts for Olefin Metathesis
Journal of the American Chemical Society2005Vol. 127(34), pp. 11882–11883
Citations Over TimeTop 1% of 2005 papers
Abstract
Ruthenium alkylidene complexes containing one aryloxide "pseudohalide" ligand catalyze ring-closing metathesis of diene and ene-yne substrates with exceptionally high efficiency. Chromatographic removal of Ru residues is unexpectedly facile, offering a convenient means of isolating pure organic products in high yields.
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