Mixed-Metal Triangular Trinuclear Complexes: Dimers of Gold−Silver Mixed-Metal Complexes from Gold(I) Carbeniates and Silver(I) 3,5-Diphenylpyrazolates
Journal of the American Chemical Society2005Vol. 127(14), pp. 5012–5013
Citations Over TimeTop 10% of 2005 papers
Abstract
Dimers of trinuclear mixed gold-silver compounds are obtained by the reaction of a gold(I) carbeniate, [Au(mu-C(OEt)=NC6H4-p-CH3)]3, with a silver(I) pyrazolate, [Ag(mu-3,5-Ph2pz)]3. The crystalline products are the mixed-metal species Au(carb)Ag2(mu-3,5-Ph2pz)2 and Au2(carb)2Ag(mu-3,5-Ph2pz)CCH2Cl2.
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