The Total Synthesis of Gambierol
Journal of the American Chemical Society2004Vol. 127(3), pp. 848–849
Citations Over TimeTop 10% of 2004 papers
Abstract
This communication describes the total synthesis of the marine polyether toxin, gambierol. This work couples our iterative C-glycoside/enol ether-olefin metathesis strategy to the subunits with a unique olefin metathesis/carbonyl olefination reaction to bring the subunits together.
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