The Role of F-Centers in Catalysis by Au Supported on MgO
Journal of the American Chemical Society2005Vol. 127(6), pp. 1604–1605
Citations Over TimeTop 1% of 2005 papers
Abstract
A correlation is found between the activity of Au clusters for the catalytic oxidation of CO and the concentration of F-centers in the surface of a MgO support. These results are consistent with recent theoretical results showing that F-centers in MgO serve to anchor Au clusters and control their charge state by partial transfer of charge from the substrate F-center to the Au cluster.
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