Anion-Templated Assembly of a [2]Catenane
Journal of the American Chemical Society2004Vol. 126(47), pp. 15364–15365
Citations Over TimeTop 10% of 2004 papers
Abstract
The first example of a [2]catenane structure to be synthesized using anion templation is described. The nature of the anion template is demonstrated to be crucial to the assembly process, with only chloride anion producing the [2]catenane in acceptable yield. Anion binding studies reveal a dramatic catenation effect on anion selectivity properties as compared to a noncatenated acyclic receptor.
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