Rationally Designed Ligands for Asymmetric Iridium-Catalyzed Hydrogenation of Olefins
Journal of the American Chemical Society2004Vol. 126(44), pp. 14308–14309
Citations Over TimeTop 10% of 2004 papers
Abstract
A new class of chiral N,P-ligands for the Ir-catalyzed asymmetric hydrogenation of aryl alkenes has been developed. These new ligands proved to be highly efficient and tolerates a broad range of substrates. The enantiomeric excesses are in the range of the best ever reported. The results can be rationalized with the proposed selectivity model.
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