Palladium-Catalyzed Oxygenation of Unactivated sp3 C−H Bonds
Journal of the American Chemical Society2004Vol. 126(31), pp. 9542–9543
Citations Over TimeTop 1% of 2004 papers
Abstract
This communication describes a new palladium-catalyzed method for the oxygenation of unactivated sp3 C-H bonds. A wide variety of alkane substrates containing readily available oxime and/or pyridine directing groups are oxidized with extremely high levels of chemo-, regio-, and in some cases diastereoselectivity. The substrate scope of these reactions is discussed, and the high selectivities are rationalized on the basis of the requirements of putative palladium alkyl intermediates.
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