N-Boc-l-Valine-Connected Amidomonophosphane Rhodium(I) Catalyst for Asymmetric Arylation of N-Tosylarylimines with Arylboroxines
Journal of the American Chemical Society2004Vol. 126(26), pp. 8128–8129
Citations Over TimeTop 10% of 2004 papers
Abstract
A catalytic asymmetric arylation of sterically tuned imines with arylboroxines was developed by using N-Boc-l-valine-connected amidomonophosphane rhodium(I) catalyst in n-PrOH. The TMS group used for the steric tuning of imines is convertible to other functionalities that are applicable as a key foothold for the carbon-carbon bond-forming coupling reactions.
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