Intramolecular Reductive Nitrosylation: Reaction of Nitric Oxide and a Copper(II) Complex of a Cyclam Derivative with Pendant Luminescent Chromophores
Journal of the American Chemical Society2004Vol. 126(21), pp. 6564–6565
Citations Over TimeTop 10% of 2004 papers
Abstract
The base-catalyzed reaction of nitric oxide with the Cu(II) complex Cu(DAC)2+ (DAC = 1,8-bis(9-anthracyl-methyl)-(1,4,8,11-tetraazacyclotetradecane)) leads to reduction of the metal center and the unexpected intramolecular nitrosylation of a secondary amine.
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