Catalytic Enantioselective Hydrostannation of Cyclopropenes
Journal of the American Chemical Society2004Vol. 126(12), pp. 3688–3689
Citations Over TimeTop 10% of 2004 papers
Abstract
The first examples of catalytic enantioselective hydrostannation of the C=C double bond of cyclopropenes has been demonstrated. This method allows for the efficient synthesis of 2,2-disubstituted cyclopropylstannanes with high degrees of diastereo- and enantioselectivity. The facial selectivity of this reaction is entirely controlled by steric factors. A variety of functional groups at C-3 of the cyclopropenes were tolerated.
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