Electrostatic Control of Aromatic Stacking Interactions
Journal of the American Chemical Society2005Vol. 127(24), pp. 8594–8595
Citations Over TimeTop 1% of 2005 papers
Abstract
A supramolecular approach has been used to investigate the free energies of intermolecular aromatic stacking interactions. Chemical double mutant cycles have been used to measure the effect of a range of substituents on face-to-face stacking interactions with phenyl and pentafluorophenyl rings. Electrostatic effects dominate the trends in interaction energy.
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