A Metallocene-Complexed Dibismuthene: Cp2Zr(BiR)2 (Cp = C5H5; R = C6H3-2,6-Mes2)
Journal of the American Chemical Society2005Vol. 127(21), pp. 7672–7673
Citations Over TimeTop 11% of 2005 papers
Yuzhong Wang, Brandon Quillian, Xiao‐Juan Yang, Pingrong Wei, Zhongfang Chen, Chaitanya S. Wannere, Paul von Ragué Schleyer, Gregory H. Robinson
Abstract
The zirconocene-complexed dibismuthene, Cp2Zr(BiR)2 (Cp = C5H5; R = C6H3-2,6-Mes2), was prepared by the reaction of sodium metal with Cp2ZrCl2 and RBiCl2. The air- and moisture-sensitive dark reddish/brown compound is the first organometallic compound containing Bi-Zr bonds and the only example of a ZrBi2 ring. Moreover, our computations on associated model systems offer insight into the nature of the interaction of the heaviest dipnictene with a metallocene center.
Related Papers
- → Synthesis and Structures of Cycloalkylidene‐Bridged Cyclopentadienyl Metallocene Catalysts: Effects of the Bridges of Ansa‐Metallocene Complexes on the Catalytic Activity for Ethylene Polymerization(2004)24 cited
- → Study of the catalytic species metallocene/MAO and metallocene/TMA by cyclic voltammetry(2003)16 cited
- → Heterogeneity of active species in metallocene catalysts(1995)17 cited
- → HOMO AND COPOLYMERIZATION OF OLEFINS AND CYCLO-OLEFINS BY HOMOGENEOUS METALLOCENE AND HALF-METALLOCENE CATALYSTS(2012)
- → Theoretical and experimental prediction of the redox potentials of metallocene compounds(2017)