Design and Synthesis of a Thermally Stable Organic Electride
Journal of the American Chemical Society2005Vol. 127(35), pp. 12416–12422
Citations Over TimeTop 13% of 2005 papers
Abstract
An electride has been synthesized that is stable to auto-decomposition at room temperature. The key was the theoretically directed synthesis of a per-aza analogue of cryptand[2.2.2] in which each of the linking arms contains a piperazine ring. This complexant was designed to provide strong complexation of Na+ via pre-organization of a "crypt" that contains eight nonreducible tertiary amine nitrogens. The structure and properties indicate that, as with other electrides, the "anions" are electrons trapped in the cavities formed by close-packing of the complexed cations. The isostructural sodide, with Na- anions in the cavities, is also stable at and above room temperature.
Related Papers
- A GEOMETRIC MEAN IN THE FURUTA INEQUALITY(2002)
- Susquehanna Chorale Spring Concert "Roots and Wings"(2017)
- Коммуникaтивно- прaгмaтический aнaлиз дипломaтических бумaг (нa основе вербaльных нот)(2018)
- → ФОРМИРОВAНИЕ ГОТОВНОСТИ БУДУЩИХ ПЕДAГОГОВ К ОРГAНИЗAЦИИ РAБОТЫ ПО РAЗВИТИЮ ВAЛЕОЛОГИЧЕСКОЙ КУЛЬТУРЫ ШКОЛЬНИКОВ(2023)