Intermolecular C−N Addition of Amides and S−N Addition of Sulfinamides to Arynes
Journal of the American Chemical Society2005Vol. 127(38), pp. 13112–13113
Citations Over TimeTop 10% of 2005 papers
Abstract
An efficient, mild, transition-metal-free method has been developed for the intermolecular C-N sigma-bond addition of amides and S-N sigma-bond addition of sulfinamides to arynes to form one C-C bond and one heteroatom-carbon bond in one step at room temperature. Evidence for a stepwise mechanism is provided.
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