Different Adsorption Behaviors of Methane and Carbon Dioxide in the Isotypic Nanoporous Metal Terephthalates MIL-53 and MIL-47
Journal of the American Chemical Society2005Vol. 127(39), pp. 13519–13521
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Sandrine Bourrelly, Philip L. Llewellyn, Christian Serre, Franck Millange, Thierry Loiseau, Gérard Férey
Abstract
A distinct step in the isotherm occurs during the adsorption of CO2 on MIL-53 at 304 K. Such behavior is neither observed during the adsorption of CH4 on MIL-53 nor during the adsorption on the isostructural MIL-47. This phenomenon seems to be due to a different mechanism than that of previous adsorption steps on MOF samples. It is suggested that a breathing behavior is induced in MIL-53 during CO2 adsorption.
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