Palladium(II)-Catalyzed Intramolecular Diamination of Unfunctionalized Alkenes
Journal of the American Chemical Society2005Vol. 127(42), pp. 14586–14587
Citations Over TimeTop 1% of 2005 papers
Abstract
Intramolecular diamination reactions are described which yield cyclic ureas as direct products of an oxidative alkene transformation in the presence of palladium acetate and iodosobenzene diacetate as terminal oxidant. The reaction is truly catalytic in metal catalyst and represents the proof of principle for this elusive type of alkene oxidation.
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