Proton Abstraction Mechanism for the Palladium-Catalyzed Intramolecular Arylation
Journal of the American Chemical Society2006Vol. 128(4), pp. 1066–1067
Citations Over TimeTop 1% of 2006 papers
Abstract
Under the usual conditions, the Pd-catalyzed arylation does not involve an electrophilic aromatic substitution reaction. On the basis of DFT calculations, we propose a mechanism for the Pd-catalyzed arylation that involves a proton abstraction by a carbonate or related ligand and that provides a satisfactory explanation for the experimental data.
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