Metal-Mediated Efficient Synthesis, Structural Characterization, and Skeletal Rearrangement of Octasubstituted Semibullvalenes
Journal of the American Chemical Society2006Vol. 128(14), pp. 4564–4565
Citations Over TimeTop 10% of 2006 papers
Abstract
The first metal-mediated efficient synthesis of octasubstituted semibullvalenes, including octaalkyl and mixed tetraalkyl and tetraphenyl derivatives, was developed. The structures of these semibullvalenes were determined by single-crystal X-ray structural analysis. Their intramolecular skeletal rearrangement and reaction chemistry were investigated.
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