An S = 6 Cyanide-Bridged Octanuclear FeIII4NiII4 Complex that Exhibits Slow Relaxation of the Magnetization
Journal of the American Chemical Society2006Vol. 128(13), pp. 4214–4215
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Dongfeng Li, Sean Parkin, Guangbin Wang, G.T. Yee, Rodolphe Clérac, Wolfgang Wernsdorfer, Stephen M. Holmes
Abstract
The synthesis and structural and magnetic characterization of an S = 6 cyanide-bridged octanuclear FeIII4NiII4 (1) complex is described. Ac susceptibility and mu-SQUID measurements suggest that fast magnetization relaxation is present in zero-field due to quantum tunneling of the ground spin state (QTM) while application of small magnetic fields induces slow relaxation of the magnetization.
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