Efficient Electronic Communication between Two Identical Ferrocene Centers in a Hydrogen-Bonded Dimer
Journal of the American Chemical Society2006Vol. 128(9), pp. 2820–2821
Citations Over TimeTop 10% of 2006 papers
Abstract
A novel ferrocene derivative that contains a donor-donor-acceptor-acceptor (DDAA) hydrogen bonding motif forms highly stable, noncovalent dimers in chloroform and dichloromethane solutions. Its voltammetric behavior and the observation of an intervalence charge-transfer band reveal that the two equivalent ferrocene centers in the hydrogen-bonded dimer exhibit a surprisingly efficient level of electronic communication.
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