A Large Protonated Water Cluster H+(H2O)27 in a 3D Metal−Organic Framework
Journal of the American Chemical Society2006Vol. 128(41), pp. 13318–13319
Citations Over TimeTop 10% of 2006 papers
Abstract
A large protonated water cluster, H+(H2O)27, has been trapped and stabilized within the well-modulated cavity of a 3D metal-organic framework formed by cobalt(II) and 4,4'-bipyridine-N,N'-dioxide with a globular Keggin structure [PW12O4]3- anion as template. The structurally characterized protonated water cluster might comprise a (H2O)26 shell with Oh symmetry and a monowater core within the center which is suggested to be a hydronium ion with the Eigen model.
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