Nanofibril Self-Assembly of an Arylene Ethynylene Macrocycle
Journal of the American Chemical Society2006Vol. 128(20), pp. 6576–6577
Citations Over TimeTop 10% of 2006 papers
Kaushik Balakrishnan, Aniket Datar, Wei Zhang, Xiaomei Yang, Tammene Naddo, Jialing Huang, Jian‐Min Zuo, Max Yen, Jeffrey S. Moore, Ling Zang
Abstract
Nanofibril structures have been fabricated from an arylene ethynylene macrocycle (AEM), which consists of a square frame corner-joined by four carbazole moieties. The fabrication was performed through a gelating process by cooling a warm, homogeneous solution in cyclohexane at high temperature (e.g., 100 degrees C) to room temperature. During the gelation, the molecules become organized, with optimal pi-pi stacking in cooperation with the side-chain association. The favorable pi-pi stacking facilitates the 1D growth of molecular assembly.
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