Characterization of the Bis-Silylated Endofullerene Sc3N@C80
Journal of the American Chemical Society2006Vol. 128(30), pp. 9919–9925
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Takatsugu Wakahara, Yuko Iiduka, Ozora Ikenaga, Tsukasa Nakahodo, Akihiro Sakuraba, Takahiro Tsuchiya, Yutaka Maeda, Masahiro Kako, Takeshi Akasaka, Kenji Yoza, Ernst Horn, Naomi Mizorogi, Shigeru Nagase
Abstract
The photochemical reaction of Sc(3)N@C(80) with 1,1,2,2-tetramesityl-1,2-disilirane affords the adduct as a bis-silylated product. The adduct was characterized by NMR spectroscopy and single-crystal X-ray structure analysis. The dynamic behavior of the disilirane moiety and the encapsulated Sc(3)N cluster were also investigated. The unique redox property of the adduct is reported by means of CV and DPV. Experimental results were confirmed by density functional calculations.
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