Catalytic Asymmetric Synthesis of Ferrocenes and P-Stereogenic Bisphosphines
Journal of the American Chemical Society2006Vol. 128(29), pp. 9336–9337
Citations Over TimeTop 10% of 2006 papers
Abstract
The catalytic asymmetric synthesis of planar chiral ferrocenes and P-stereogenic phosphines and bisphosphines (important classes of chiral ligands for metal-catalyzed asymmetric processes) is successfully demonstrated using n-BuLi or s-BuLi in combination with substoichiometric quantities (0.1-0.5 equiv) of (-)-sparteine or the (+)-sparteine surrogate.
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