Synthesis, Crystal Structure, and Nonlinear Optical Properties of Li6CuB4O10: a Congruently Melting Compound with Isolated [CuB4O10]6- Units
Journal of the American Chemical Society2006Vol. 128(35), pp. 11631–11634
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Shilie Pan, Jared P. Smit, Byron Watkins, Michael R. Marvel, Charlotte L. Stern, Kenneth R. Poeppelmeier
Abstract
Single crystals of Li(6)CuB(4)O(10) have been synthesized, and its crystal structure has been determined. Li(6)CuB(4)O(10) crystallizes in the non-centrosymmetric triclinic space group P1 (No. 1). The structure consists of isolated [CuB(4)O(10)](6)(-) polyanions that are bridged by six LiO(4) tetrahedra. Li(6)CuB(4)O(10) is a congruently melting compound. It produces SHG intensity similar to that produced by KH(2)PO(4) and is phase-matchable.
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