Nanoscale Spherical Architectures Fabricated by Metal Coordination of Multiple Dipyrrin Moieties
Journal of the American Chemical Society2006Vol. 128(31), pp. 10024–10025
Citations Over TimeTop 10% of 2006 papers
Hiromitsu Maeda, Masahiro Hasegawa, Takashi Hashimoto, Takuya Kakimoto, Satoru Nishio, Takashi Nakanishi
Abstract
Phenylethynyl-bridged dipyrrin "dimers" have performed ZnII complexation to give coordination polymers, which provided the fluorescent colloidal spherical objects in solution as well as on the substrate according to the spacer units. Using a mixture of THF and water, unique morphologies, such as bell-shaped and "golf ball"-like architectures, were observed.
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