La@C72 Having a Non-IPR Carbon Cage
Journal of the American Chemical Society2006Vol. 128(44), pp. 14228–14229
Citations Over TimeTop 10% of 2006 papers
Takatsugu Wakahara, Hidefumi Nikawa, Takashi Kikuchi, Tsukasa Nakahodo, Gul Rahman, Takahiro Tsuchiya, Yutaka Maeda, Takeshi Akasaka, Kenji Yoza, Ernst Horn, Kazunori Yamamoto, Naomi Mizorogi, Zdeněk Slanina, Shigeru Nagase
Abstract
We show here that La@C72 has a non-IPR cage, unique electronic properties, and high reactivity by the spectroscopic and X-ray crystallographic analysis and the theoretical study. The isolation of La@C72 as a stable derivative might constitute an important stepping-stone on the way to isolation of these unknown metallofullerenes and open new material science of metallofullerenes.
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