Stereocontrolled Synthesis of β-d-Mannuronic Acid Esters: Synthesis of an Alginate Trisaccharide
Journal of the American Chemical Society2006Vol. 128(40), pp. 13066–13067
Citations Over TimeTop 10% of 2006 papers
Abstract
A facile synthesis route toward beta-linked mannuronic acid oligomers using the corresponding 1-thiomannuronic acid esters in combination with the Ph2SO/Tf2O or NIS/TMSOTf reagent combinations is presented. The presence of the remotely attached carboxylic ester sufficiently influences the electronic environment to allow good to excellent beta-selectivities.
Related Papers
- → Synthesis of a common trisaccharide fragment of glycoforms of the outer core region of the Pseudomonas aeruginosa lipopolysaccharide(2006)39 cited
- → Synthesis of a carboxyl linker containing Pk trisaccharide(2004)14 cited
- → Synthesis of a trisaccharide related to the antitumour antibiotic, aclacinomycin A(1983)7 cited
- → Structural Studies of Trisaccharide of Leptaculatin(1994)1 cited