Controlling Regiochemistry in Negishi Carboaluminations. Fine Tuning the Ligand on Zirconium
Journal of the American Chemical Society2006Vol. 128(48), pp. 15396–15398
Citations Over TimeTop 16% of 2006 papers
Abstract
The species on the zirconocene catalyst is changed from two Cp's to the Brintzinger ligand and catalytic amounts of MAO are used to usually effect a >99% regiocontrol of Negishi carboaluminations of 1-alkynes in toluene.
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