Structure and Catalytic Function of Re-Oxo Species Grafted onto H-MFI Zeolite by Sublimation of Re₂O₇

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Abstract

Isolated Re-oxo species within spatially constrained MFI zeolite channels were synthesized via exchange with Re2O7 vapor and shown to exist as isolated Re-oxo monomers. Turnover rates and Re-oxo structures did not depend on Re content. These materials were thermally stable and catalyzed alcohol oxidation reactions at unprecedented rates and near ambient temperatures.

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