A Mechanism for Non-stoichiometry in the Lithium Amide/Lithium Imide Hydrogen Storage Reaction
Journal of the American Chemical Society2007Vol. 129(6), pp. 1594–1601
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William I. F. David, Martin O. Jones, Duncan H. Gregory, Catherine M. Jewell, Simon R. Johnson, Allan Walton, Peter P. Edwards
Abstract
We demonstrate, through structural refinement from synchrotron X-ray diffraction data, that the mechanism of the transformation between lithium amide and lithium imide during hydrogen cycling in the important Li-N-H hydrogen storage system is a bulk reversible reaction that occurs in a non-stoichiometric manner within the cubic anti-fluorite-like Li-N-H structure.
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