Hexathiapentacene: Structure, Molecular Packing, and Thin-Film Transistors
Journal of the American Chemical Society2006Vol. 128(49), pp. 15576–15577
Citations Over TimeTop 1% of 2006 papers
Abstract
In this communication we report the electrical characteristics of hexathiapentacene (HTP) and emphasize the unusual chemical structure and molecular packing. We report field-effect mobilities as high as 0.04 cm2 V-1 s-1 and current on/off ratios of >105. With crystallographic evidence of unusually long S-S bonds compared to normal S-S bonds, we have suggested a unique resonance structure similar to trithiapentalene, which well explains the bonding characteristics of HTP. This work appears to be the first to determine its molecular structure/packing mode and to study its application in organic transistors.
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