Stable Single-Layer Light-Emitting Electrochemical Cell Using 4,7-Diphenyl-1,10-phenanthroline-bis(2-phenylpyridine)iridium(III) Hexafluorophosphate
Journal of the American Chemical Society2006Vol. 128(46), pp. 14786–14787
Citations Over TimeTop 10% of 2006 papers
Henk J. Bolink, Luca Cappelli, Eugenio Coronado, Michaël Grätzel, Enrique Ortı́, Rubén D. Costa, Pedro M. Viruela, Mohammad Khaja Nazeeruddin
Abstract
A significant improvement in the stability of a light emitting electrochemical cell was achieved by utilizing a novel iridium(III) complex: 4,7-diphenyl-1,10-phenanthroline-bis(2-phenylpyridine)iridium(III) hexafluorophosphate. The enhanced device stability is correlated by means of DFT studies to be related to a more efficient shielding of the reactive LUMO of the complex.
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