Mechanical Control of Enantioselectivity of Amino Acid Recognition by Cholesterol-Armed Cyclen Monolayer at the Air-Water Interface
Journal of the American Chemical Society2006Vol. 128(45), pp. 14478–14479
Citations Over TimeTop 10% of 2006 papers
Tsuyoshi Michinobu, Satoshi Shinoda, Takashi Nakanishi, Jonathan P. Hill, Kazuko Fujii, Tomoko N. Player, Hiroshi Tsukube, Katsuhiko Ariga
Abstract
Monolayers of the cholesterol-armed cyclen Na+ complex at the air-water interface display a remarkable, surface pressure dependent enantioselectivity of amino acid recognition. Upon compression of the monolayer, the binding constants of amino acids increase accompanying an inversion of chiral selectivity from the d- to l-form in the case of valine.
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